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Are non-chromium catalysts efficient for ester hydrogenolysis?

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22320%2F18%3A43916351" target="_blank" >RIV/60461373:22320/18:43916351 - isvavai.cz</a>

  • Alternative codes found

    RIV/60461373:22350/18:43916351

  • Result on the web

    <a href="https://iceti.vscht.cz/files/uzel/0040841/0009~~K07KL8o7vDY73tPZNcTTyMDQQrfMCAA.pdf?redirected" target="_blank" >https://iceti.vscht.cz/files/uzel/0040841/0009~~K07KL8o7vDY73tPZNcTTyMDQQrfMCAA.pdf?redirected</a>

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Are non-chromium catalysts efficient for ester hydrogenolysis?

  • Original language description

    Typical catalysts used for ester hydrogenolysis are based on copper and chromium oxides. This combination is highly efficient, but problematic because of the production of hexavalent-chromium-containing liquid and solid waste that is difficult to dispose. Therefore, we studied if CuZnAl catalysts as non-chromium alternative could exhibit activity comparable to that of CuO-Cr2O3 being more eco-friendly. For this purpose, a series of CuZnAl catalysts was prepared by a co-precipitation method. The prepared CuZnAl, commercial CuZnAl and commercial CuO-Cr2O3 catalysts were tested in hydrogenolysis of dimethyl adipate. Experiments over CuZnAl catalysts showed DMA conversion comparable to that obtained over CuO-Cr2O3 under the tested reaction conditions (175-205 °C, 16 MPa).

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

  • OECD FORD branch

    20702 - Petroleum engineering (fuel, oils)

Result continuities

  • Project

    <a href="/en/project/GA17-05704S" target="_blank" >GA17-05704S: Investigation and optimization of promoted CuZnAl hydrogenation catalysts</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    ICETI 2018 - 2nd International Conference on Environmental Technology and Innovations

  • ISBN

    978-80-7592-034-8

  • ISSN

  • e-ISSN

    neuvedeno

  • Number of pages

    6

  • Pages from-to

    48-53

  • Publisher name

    Vysoká škola chemicko-technologická v Praze

  • Place of publication

    Praha

  • Event location

    Praha

  • Event date

    Nov 21, 2018

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article