Catalytic Transfer Hydrogenation of Furfural over Co3O4−Al2O3 Hydrotalcite-derived Catalyst

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22320%2F20%3A43920346" target="_blank" >RIV/60461373:22320/20:43920346 - isvavai.cz</a>

Result on the web

<a href="http://10.1002/cctc.201902033" target="_blank" >http://10.1002/cctc.201902033</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/cctc.201902033" target="_blank" >10.1002/cctc.201902033</a>

Result language

angličtina

Original language name

Catalytic Transfer Hydrogenation of Furfural over Co3O4−Al2O3 Hydrotalcite-derived Catalyst

Original language description

The hydrogenation of furfural by catalytic hydrogen transfer to produce furfuryl alcohol has been investigated over a series of mixed oxides derived from hydrotalcite catalysts. Three different catalysts containing Ni, Co and Zn phases on an Al-rich amorphous support were synthesized and characterised. The catalytic performances were evaluated in a batch stirred reactor using 2-propanol as a solvent and hydrogen donor, with Co3O4−Al2O3 showing the highest activity and selectivity to FA (74 % yield; 97 % selectivity). The effects of temperature (T=120–180 °C) and reaction time (t=30 min–24 h) were also studied, reaching a FA maximum yield of 92 % at 150 °C after 24 h. The Co3O4−Al2O3 catalyst showed a loss of activity after the first run, which can be easily restored by a simple calcination treatment. The results establish a catalytic route to produce valuable furfuryl alcohol over 3d-transition metal-based catalysts without any external hydrogen supply. © 2019 Wiley-VCH Verlag GmbH &amp; Co. KGaA, Weinheim

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

10403 - Physical chemistry

Project

—

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2020

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

ChemCatChem

ISSN

1867-3880

e-ISSN

—

Volume of the periodical

12

Issue of the periodical within the volume

5

Country of publishing house

DE - GERMANY

Number of pages

9

Pages from-to

1467-1475

UT code for WoS article

000507642900001

EID of the result in the Scopus database

2-s2.0-85078589868