From Theory to Practice: Leveraging Chemical Principles To Improve the Performance of Peroxydisulfate-Based In Situ Chemical Oxidation of Organic Contaminants
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22320%2F24%3A43927727" target="_blank" >RIV/60461373:22320/24:43927727 - isvavai.cz</a>
Result on the web
<a href="https://pubs.acs.org/doi/10.1021/acs.est.3c07409" target="_blank" >https://pubs.acs.org/doi/10.1021/acs.est.3c07409</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.est.3c07409" target="_blank" >10.1021/acs.est.3c07409</a>
Alternative languages
Result language
angličtina
Original language name
From Theory to Practice: Leveraging Chemical Principles To Improve the Performance of Peroxydisulfate-Based In Situ Chemical Oxidation of Organic Contaminants
Original language description
In situ chemical oxidation (ISCO) using peroxydisulfate has become more popular in the remediation of soils and shallow groundwater contaminated with organic chemicals. Researchers have studied the chemistry of peroxydisulfate and the oxidative species produced upon its decomposition (i.e., sulfate radical and hydroxyl radical) for over five decades, describing reaction kinetics, mechanisms, and product formation in great detail. However, if this information is to be useful to practitioners seeking to optimize the use of peroxydisulfate in the remediation of hazardous waste sites, the relevant conditions of high oxidant concentrations and the presence of minerals and solutes that affect radical chain reactions must be considered. The objectives of this Review are to provide insights into the chemistry of peroxydisulfate-based ISCO that can enable more efficient operation of these systems and to identify research needed to improve understanding of system performance. By gaining a deeper understanding of the underlying chemistry of these complex systems, it may be possible to improve the design and operation of peroxydisulfate-based ISCO remediation systems. © 2023 The Authors. Published by American Chemical Society.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
20701 - Environmental and geological engineering, geotechnics
Result continuities
Project
<a href="/en/project/GA23-05901S" target="_blank" >GA23-05901S: Degradation of benzophenone-type UV filters in aqueous solutions using peroxydisulfate</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ENVIRONMENTAL SCIENCE & TECHNOLOGY
ISSN
0013-936X
e-ISSN
1520-5851
Volume of the periodical
58
Issue of the periodical within the volume
1
Country of publishing house
US - UNITED STATES
Number of pages
15
Pages from-to
17-32
UT code for WoS article
001139504200001
EID of the result in the Scopus database
2-s2.0-85181018392