A Stereocontrolled Access to alpha-C-(1-3) Linked Disaccharides Containing 2-Deoxyhexopyranoses
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22330%2F03%3A00008438" target="_blank" >RIV/60461373:22330/03:00008438 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
A Stereocontrolled Access to alpha-C-(1-3) Linked Disaccharides Containing 2-Deoxyhexopyranoses
Original language description
Protected alpha-D-glucopyranosylacetaldehyde was converted by Wittig reaction with (thiazol 2 yl)carbonylmethylenetriphenyl phosphorane into the corresponding substituted 1-oxa-1,3-butadiene which by hetero-Diels-Alder reaction with ethyl vinyl ether afforded a mixture of two diastereoisomeric dihydropyran derivatives. These were separated by chromatography and the thiazol ring was transformed into an aldehyde group. Subsequent hydroboration afforded alpha-C-(1-3)-linked disaccharides containing 2-deoxyhexopyranoses of D- or L- configuration.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Synlett
ISSN
0936-5214
e-ISSN
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Volume of the periodical
2003
Issue of the periodical within the volume
7
Country of publishing house
US - UNITED STATES
Number of pages
4
Pages from-to
963-966
UT code for WoS article
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EID of the result in the Scopus database
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