Synthesis of Graphene Oxide by Oxidation of Graphite with Ferrate (VI) Compounds: Myth or Reality?

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22330%2F16%3A43901890" target="_blank" >RIV/60461373:22330/16:43901890 - isvavai.cz</a>

Alternative codes found

RIV/60461373:22310/16:43901890

Result on the web

<a href="http://onlinelibrary.wiley.com/doi/10.1002/anie.201603496/full" target="_blank" >http://onlinelibrary.wiley.com/doi/10.1002/anie.201603496/full</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1002/anie.201603496" target="_blank" >10.1002/anie.201603496</a>

Result language

angličtina

Original language name

Synthesis of Graphene Oxide by Oxidation of Graphite with Ferrate (VI) Compounds: Myth or Reality?

Original language description

It is well established that graphene oxide can be prepared by the oxidation of graphite using permanganate or chlorate in an acidic environment. Recently, however, the synthesis of graphene oxide using potassium ferrate(VI) ions has been reported. Herein, we critically replicate and evaluate this new ferrate(VI) oxidation method. In addition, we test the use of potassium ferrate(VI) for the synthesis of graphene oxide under various experimental routes. The synthesized materials are analyzed by a number of analytical methods in order to confirm or disprove the possibility of synthesizing graphene oxide by the ferrate(VI) oxidation route. Our results confirm the unsuitability of using ferrate(VI) for the oxidation of graphite on graphene oxide because of its high instability in an acidic environment and low oxidation power in neutral and alkaline environments.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

<a href="/en/project/GA15-09001S" target="_blank" >GA15-09001S: Chemical modifications of graphene based materials: Synthesis of graphane and halogengraphene</a><br>

Continuities

S - Specificky vyzkum na vysokych skolach

Publication year

2016

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Angewandte Chemie-International Edition

ISSN

1433-7851

e-ISSN

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Volume of the periodical

55

Issue of the periodical within the volume

39

Country of publishing house

DE - GERMANY

Number of pages

5

Pages from-to

11965-11969

UT code for WoS article

000384713100047

EID of the result in the Scopus database

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