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Physicochemical approach to alkaline flocculation of Chlorella vulgaris induced by calcium phosphate precipitates

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22330%2F18%3A43915568" target="_blank" >RIV/60461373:22330/18:43915568 - isvavai.cz</a>

  • Alternative codes found

    RIV/67985858:_____/18:00487866 RIV/67985874:_____/18:00487866 RIV/00216208:11310/18:10378434

  • Result on the web

    <a href="https://www.sciencedirect.com/science/article/pii/S0927776518301437?via%3Dihub" target="_blank" >https://www.sciencedirect.com/science/article/pii/S0927776518301437?via%3Dihub</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.colsurfb.2018.03.007" target="_blank" >10.1016/j.colsurfb.2018.03.007</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Physicochemical approach to alkaline flocculation of Chlorella vulgaris induced by calcium phosphate precipitates

  • Original language description

    Alkaline flocculation has been studied due to its potential as a low-cost harvesting method for microalgae. However, surface properties (zeta potential, contact angles) as inputs into physicochemical interaction models have not yet been applied systematically. In this work, forced alkaline flocculation of the freshwater microalgae Chlorella vulgaris induced by calcium phosphate precipitates was studied as a model system. Response surface methodology was used to quantify the effect of independent variables (concentration of Ca2+ (0.5-0.5 mM) and PO43- (0.05-0.35 mM), pH (8-12) and ionic strength (1-19 mM)) on the zeta potential (ZP) of microalgae, and the turbidity (T) of inorganic precipitates. Flocculation tests and their modified versions were carried out. The flocculation efficiencies obtained were interpreted with respect to predictions of physicochemical interaction models. It was found that flocculation was possible under conditions where appropriate precipitates were formed in the presence of cells. Under these conditions, flocculation of negatively charged Chlorella vulgaris was induced not only by positively charged, but also by negatively charged calcium phosphate precipitates at an early phase of nucleation. The driving force for interactions between oppositely charged cells and precipitate particles was electrostatic attraction, while the attraction between equally charged entities may have resulted from a negative total balance of apolar (Lifsitz-van der Waals) and polar (acid-base) interactions. Medium components did not interfere with flocculation, while cellular organic matter decreased flocculation efficiency only to a very limited extent.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20901 - Industrial biotechnology

Result continuities

  • Project

    <a href="/en/project/GA18-05007S" target="_blank" >GA18-05007S: Influence of algal organic matter on properties of flocs formed during coagulation/flocculation in water treatment</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Colloids and Surfaces B: Biointerfaces

  • ISSN

    0927-7765

  • e-ISSN

  • Volume of the periodical

    166

  • Issue of the periodical within the volume

    June 1 2018

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    7

  • Pages from-to

    54-60

  • UT code for WoS article

    000432505900008

  • EID of the result in the Scopus database