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Liquid-liquid equilibria in ternary systems nitromethane + water + 1-alcohols. Measurement, correlation and prediction.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F02%3A00007103" target="_blank" >RIV/60461373:22340/02:00007103 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Liquid-liquid equilibria in ternary systems nitromethane + water + 1-alcohols. Measurement, correlation and prediction.

  • Original language description

    Liquid - liquid equilibria (LLE) in ternary systems nitromethane + water + 1-alcohols show theoretically interesting thermal behaviour. The aim of this work was to determine LLE in three ternary systems nitromethane + water + 1-alcohols (1-butanol, 1-hexanol, 1-octanol) at 298.15 K and to compare the results with equilibrium data predicted by the modified Wilson equation and the modified UNIFAC (Dortmund) contribution method. Two experimental methods have been employed to determine LLE in the ternary systems: the direct analytical method and the titration method. The experimental data were correlated on the basis of the binary system parameters obtained by means of the modified Wilson equation together with the ternary corrections. For the thermodynamic description of the binary subsystems our experimental and literature data on LLE together with available literature data on vapour - liquid equilibrium and excess enthalpy were employed.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2002

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    The CD with full texts of the contributions of the 15th International Congress of Chemical and Process Engineering CHISA 2002

  • ISBN

    80-86059-33-2

  • ISSN

  • e-ISSN

  • Number of pages

    16

  • Pages from-to

  • Publisher name

    Česká společnost chemického inženýrství

  • Place of publication

    Praha, ČR

  • Event location

    Praha, ČR

  • Event date

    Aug 25, 2002

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article