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Solid-liquid and liquid-liquid equilibrium in the formamide-acetophenone system

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F06%3A00016685" target="_blank" >RIV/60461373:22340/06:00016685 - isvavai.cz</a>

  • Alternative codes found

    RIV/67985858:_____/06:00091622

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Solid-liquid and liquid-liquid equilibrium in the formamide-acetophenone system

  • Original language description

    Solid-liquid and liquid-liquid equilibrium was determined in the binary system formamide-acetophenone. The s-l equilibrium was measured by recording time-temperature cooling and warming curves. The l-l equilibrium was obtained in a wide range of temperatures by the turbidity method. A considerable supercooling preceding solidification made it possible to examine metastable l-l equilibrium yet at temperatures lower than the solidus ones. Activity coefficients evaluated from the stable region of l-l equilibrium were correlated by Novák's modification of the Wilson equation. Calculation of the s-l equilibrium was performed with the obtained parameters. Heat capacity of solid and liquid acetophenone was measured and its dependence on temperature is given.The transition enthalpy between two solid modifications of acetophenone is also given.

  • Czech name

    Rovnováha kapalina-tuhá fáze a kapalina-kapalina v systému formamid - acetofenon

  • Czech description

    Byla měřena rovnováha kapalina-pevná fáze a kapalina-kapalina v systému formamid-acetofenon. Rovnováha kapalina-pevná fáze byla měřena pomocí křivek

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2006

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Collection of Czechoslovak Chemical Communications

  • ISSN

    0010-0765

  • e-ISSN

  • Volume of the periodical

    71

  • Issue of the periodical within the volume

    9

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    9

  • Pages from-to

    1350-1358

  • UT code for WoS article

  • EID of the result in the Scopus database