The ground state rotational spectrum of the fluorosulfate radical
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F09%3A00021802" target="_blank" >RIV/60461373:22340/09:00021802 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
The ground state rotational spectrum of the fluorosulfate radical
Original language description
The rotational spectra of the fluorosulfate FSO3? molecular radical in its vibronic ground state were measured in the millimeter-wave region and analyzed in detail using the matrix elements of the rotational, fine, and hyperfine Hamiltonian terms. The analysis of the assigned transition frequencies made it possible to derive very precise values of the rotational, centrifugal distortion and fine structure constants and to confirm the C3v molecular symmetry of the vibronic ground state unambiguously. In addition, an effective parameter of the ?A1-A2 splitting? was determined. The rotational transitions of the FSO3? free radical were observed, identified, and analyzed for the first time.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2009
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Chemical Physics
ISSN
0021-9606
e-ISSN
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Volume of the periodical
130
Issue of the periodical within the volume
18
Country of publishing house
US - UNITED STATES
Number of pages
9
Pages from-to
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UT code for WoS article
000266263200023
EID of the result in the Scopus database
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