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Partial molar volumes of organic solutes in water. XX. Glycine(aq) and L-alanine(aq) at temperatures T = 298 K to 443 K and at pressures up to 30 MPa.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F10%3A00023345" target="_blank" >RIV/60461373:22340/10:00023345 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Partial molar volumes of organic solutes in water. XX. Glycine(aq) and L-alanine(aq) at temperatures T = 298 K to 443 K and at pressures up to 30 MPa.

  • Original language description

    Density data for dilute aqueous solutions of two amino acids (glycine, L-alanine) obtained using a flow vibrating-tube densimeter are presented together with partial molar volumes at infinite dilution (standard molar volumes, V0m,2) calculated from the measured data. The experiments were performed at temperatures from T = 298 K up to T = 443 K at pressures close to the saturation line of water, at pressures in the range from 15 MPa to 17 MPa, and at 30 MPa. Values of an analogue of isothermal compressibility, ?0T,2 = -(1/V0m,2)(V0m,2/p)T, are also evaluated. Maxima on the curves V0m,2(T) and ?0T,2(T) are observed and discussed. The new data along with literature values of standard molar volumes and heat capacities are used for generating the recommended parameterization of an equation of state for standard molar thermodynamic properties of the aqueous amino acids.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BJ - Thermodynamics

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Chemical Thermodynamics

  • ISSN

    0021-9614

  • e-ISSN

  • Volume of the periodical

    42

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    10

  • Pages from-to

  • UT code for WoS article

    000272898600007

  • EID of the result in the Scopus database