Extraction of Calcium and Strontium into Phenyltrifluoromethyl Sulfone by Using Synergistic Mixture of Hydrogen Dicarbollylcobaltate and ?Classical? CMPO
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F10%3A00023384" target="_blank" >RIV/60461373:22340/10:00023384 - isvavai.cz</a>
Alternative codes found
RIV/46356088:_____/10:#0001014 RIV/49777513:23520/10:00503624
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Extraction of Calcium and Strontium into Phenyltrifluoromethyl Sulfone by Using Synergistic Mixture of Hydrogen Dicarbollylcobaltate and ?Classical? CMPO
Original language description
Solvent extraction of microamounts of calcium and strontium by a phenyltrifluoromethyl sulfone (FS 13) solution of hydrogen dicarbollylcobaltate (H+B?) in the presence of octyl-phenyl-N,N-diisobutylcarbamoylmethyl phosphine oxide (?classical? CMPO, L) has been investigated. The equilibrium data have been explained assuming that the species HL+,HL2+, ML2+, ML22+ and ML32+ (M2+ = Ca2+, Sr2+) are extracted into the organic phase. The values of extraction and stability constants of the cationic complex species in FS 13 saturated with water have been determined. In the considered FS 13 medium, it was found that the stability constants of the complex species CaLn2+, where n = 1, 2, 3 and L is ?classical? CMPO, are higher than those of the corresponding complexes SrLn2+.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA104%2F09%2F0668" target="_blank" >GA104/09/0668: Design and development of extractants for radionuclides based on boron cluster anions</a><br>
Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Acta Chimica Slovenica
ISSN
1318-0207
e-ISSN
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Volume of the periodical
57
Issue of the periodical within the volume
2
Country of publishing house
SI - SLOVENIA
Number of pages
6
Pages from-to
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UT code for WoS article
000279939100030
EID of the result in the Scopus database
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