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Limiting activity coefficients of 1-chlorobutane in water and in aqueous solutions of substances involved in synthesis of ionic liquids

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F10%3A00023423" target="_blank" >RIV/60461373:22340/10:00023423 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Limiting activity coefficients of 1-chlorobutane in water and in aqueous solutions of substances involved in synthesis of ionic liquids

  • Original language description

    Limiting activity coefficients were measured for 1-chlorobutane in water and in aqueous solutions of the additives 1-methylimidazole (MeIm), ionic liquid 1-butyl-3-methylimidazolium chloride (BMImCl), and sodium chloride (NaCl) at temperatures from 273.35 to 308.15 K and additive concentrations from 0 to 0.6 mol kg-1 employing the methods of inert gas stripping and exponential saturator. The data measured in this work enabled us to establish recommended temperature dependence for limiting activity coefficients of 1-chlorobutane in water. To this end, the present data were supplemented with (i) compiled and critically evaluated limiting activity coefficient data from the literature and (ii) an estimated value of infinite dilution partial molar heat capacity and subsequently fitted to a suitable model equation. The recommended values of limiting activity coefficients and from them inferred values of solubility, Henry?s law constant, and air?water partition coefficients are reported at se

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BJ - Thermodynamics

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Fluid Phase Equilibria

  • ISSN

    0378-3812

  • e-ISSN

  • Volume of the periodical

    299

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    6

  • Pages from-to

  • UT code for WoS article

  • EID of the result in the Scopus database