Temperature Dependence of Limiting Activity Coefficients, Henry`s Law Constants, and Related Infinite Dilution Properties of Branched Pentanols in Water. Measurement, Critical Compilation, Correlation, and Recommended Data

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F10%3A00023428" target="_blank" >RIV/60461373:22340/10:00023428 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Temperature Dependence of Limiting Activity Coefficients, Henry`s Law Constants, and Related Infinite Dilution Properties of Branched Pentanols in Water. Measurement, Critical Compilation, Correlation, and Recommended Data

Original language description

Limiting activity coefficients of six branched pentanols (2-pentanol, 3-pentanol, 2-methyl-1-butanol, 3-methyl-1-butanol, 2-methyl-2-butanol, and 3-methyl-2-butanol) in water were measured at several temperatures covering the range from the melting to the normal boiling point of water. Five experimental techniques, namely, inert gas stripping, headspace analysis in two variants, the classical and the relative, Rayleigh distillation, and the method of circulation still, were employed for the purpose. A comprehensive review is further presented of experimental data on the limiting activity coefficients, infinite dilution partial molar excess enthalpies and heat capacities of these aqueous solutes. Since infinite dilution partial molar excess enthalpy data for 2-methyl-1-butanol in water are lacking in the literature, they were also determined in this work. For each pentanol isomer, the compiled data were critically evaluated and together with the data measured in this work correlated wit

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

BJ - Thermodynamics

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2010

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Chemical Engineering Data

ISSN

0021-9568

e-ISSN

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Volume of the periodical

55

Issue of the periodical within the volume

9

Country of publishing house

US - UNITED STATES

Number of pages

12

Pages from-to

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UT code for WoS article

000281567000015

EID of the result in the Scopus database

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