Rotational and Rovibrational Spectroscopy of CH3NC of the Ground and v(4)=1 Vibrational States
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F11%3A43885707" target="_blank" >RIV/60461373:22340/11:43885707 - isvavai.cz</a>
Alternative codes found
RIV/61388955:_____/11:00358329
Result on the web
<a href="http://dx.doi.org/10.1021/jp1090312" target="_blank" >http://dx.doi.org/10.1021/jp1090312</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/jp1090312" target="_blank" >10.1021/jp1090312</a>
Alternative languages
Result language
angličtina
Original language name
Rotational and Rovibrational Spectroscopy of CH3NC of the Ground and v(4)=1 Vibrational States
Original language description
The parallel vibration-rotation band v(4) of methyl isocyanide (CH3NC), with a band center at 944.9 cm(-1), was studied by FTIR spectroscopy between 890 and 980 cm(-1) in order to improve the ground-state rotational constants. Such improvement is essential for the scheduled studies of excited vibrational levels and their mutual anharmonic resonances occurring at higher values of the K rotational number. Ground-state combination differences generated from this band, spanning values of J/K from 0 to 85/13, were combined with rotational data from the literature and newly measured rotational transitions, extending the J/K range from 3/0 up to 31/14, and fitted simultaneously with a fully quantitative reproduction of the data. The infrared data of the v(4)band were analyzed together with rotational data of the v(4) = 1 level, spanning values of J/K from 4/0 to 14/12.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Physical Chemistry A
ISSN
1089-5639
e-ISSN
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Volume of the periodical
115
Issue of the periodical within the volume
6
Country of publishing house
US - UNITED STATES
Number of pages
6
Pages from-to
1063-1068
UT code for WoS article
000287066000014
EID of the result in the Scopus database
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