Interactions of Volatile Organic Compounds with the Ionic Liquid 1-Butyl-1-methylpyrrolidinium Dicyanamide
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F11%3A43891415" target="_blank" >RIV/60461373:22340/11:43891415 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/je200822w" target="_blank" >http://dx.doi.org/10.1021/je200822w</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/je200822w" target="_blank" >10.1021/je200822w</a>
Alternative languages
Result language
angličtina
Original language name
Interactions of Volatile Organic Compounds with the Ionic Liquid 1-Butyl-1-methylpyrrolidinium Dicyanamide
Original language description
Interactions of volatile organic compounds with the ionic liquid (IL) 1-butyl-1-methylpyrrolidinium dicyanamide [BMPYR][DCA] were explored through systematic gas?liquid chromatography retention measurements. Infinite dilution activity coefficients and gas?liquid partition coefficients KL of 30 selected hydrocarbons, alcohols, ketones, ethers, esters, haloalkanes, nitrogen- and sulfur-containing compounds in [BMPYR][DCA] were determined at five temperatures in the range from (318.15 to 353.15) K. Partialmolar excess enthalpies and entropies at infinite dilution were derived from the temperature dependence of the infinite dilution activity coefficient values. The Linear Free Energy Relationship (LFER) solvation model was used to correlate successfully the KL values. The LFER correlation parameters and excess thermodynamic functions were analyzed to disclose molecular interactions operating between the IL and the individual solutes. Among other ILs, [BMPYR][DCA] was identified to be a fa
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Chemical Engineering Data
ISSN
0021-9568
e-ISSN
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Volume of the periodical
56
Issue of the periodical within the volume
12
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
4909-4918
UT code for WoS article
000297608800087
EID of the result in the Scopus database
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