Kinetic description for modeling of electrochemical systems

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F11%3A43892301" target="_blank" >RIV/60461373:22340/11:43892301 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Kinetic description for modeling of electrochemical systems

Original language description

We propose a novel kinetic mechanism of electrochemical interactions. We assume fast formation and recombination of electron donors (DE-) and acceptors (AE+) on electrode surfaces. These mediators are continuously formed in the electrode matter by thermal fluctuations. The mediators DE- and AE+ enter electrochemical interactions on the electrode surfaces, where dynamics and current-voltage characteristics of a selected electrochemical system are studied. In regimes not hindered by mass transport, the characteristics are in good qualitative agreement with those given by classical Butler-Volmer kinetics.

Czech name

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Czech description

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Type

D - Article in proceedings

CEP classification

CI - Industrial chemistry and chemical engineering

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach

Publication year

2011

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Article name in the collection

Workshop Reakční a transportní jevy V

ISBN

978-80-7080-797-2

ISSN

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e-ISSN

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Number of pages

8

Pages from-to

245-252

Publisher name

VŠCHT Praha

Place of publication

Praha

Event location

Roztoky u Křivoklátu

Event date

Jun 8, 2011

Type of event by nationality

CST - Celostátní akce

UT code for WoS article

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