Interactions of volatile organic compounds with the ionic liquid 1-ethyl-3-methylimidazolium tetracyanoborate

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F12%3A43871505" target="_blank" >RIV/60461373:22340/12:43871505 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.jct.2011.09.028" target="_blank" >http://dx.doi.org/10.1016/j.jct.2011.09.028</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jct.2011.09.028" target="_blank" >10.1016/j.jct.2011.09.028</a>

Result language

angličtina

Original language name

Interactions of volatile organic compounds with the ionic liquid 1-ethyl-3-methylimidazolium tetracyanoborate

Original language description

Interactions of volatile organic compounds with the ionic liquid (IL) 1-ethyl-3-methylimidazolium tetracyanoborate [EMIM][B(CN)4] were explored through systematic GLC retention measurements. Infinite dilution activity coefficients and gas-liquid partition coefficients of 30 selected solutes in [EMIM][B(CN)4] were determined at five temperatures in the range from (318.15 to 353.15) K and respective dissolution enthalpies and entropies were derived. Reliability of our results was substantiated by additional measurements we carried out using the inert gas stripping technique, IL samples from two different batches, and careful purity checks. Since two similar experimental studies on [EMIM][B(CN)4] have emerged during the progression of this work, a uniquepossibility has arisen for direct inter-laboratory comparison of results. While the present values and those of Yan et al. (J.Chem.Thermodyn. 42(2010)817-822) show disparities as large as 30 % in limiting activity coefficient and 6 kJ.mol

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)<br>S - Specificky vyzkum na vysokych skolach

Publication year

2012

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Chemical Thermodynamics

ISSN

0021-9614

e-ISSN

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Volume of the periodical

47

Issue of the periodical within the volume

1

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

9

Pages from-to

100-108

UT code for WoS article

000299039100016

EID of the result in the Scopus database

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