Does adsorption in a single nanogroove exhibit hysteresis?

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F12%3A43894087" target="_blank" >RIV/60461373:22340/12:43894087 - isvavai.cz</a>
Alternative codes found
RIV/67985858:_____/12:00393285
Result on the web
<a href="http://jcp.aip.org/resource/1/jcpsa6/v137/i21/p214704_s1" target="_blank" >http://jcp.aip.org/resource/1/jcpsa6/v137/i21/p214704_s1</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1063/1.4769257" target="_blank" >10.1063/1.4769257</a>

Result language
angličtina
Original language name
Does adsorption in a single nanogroove exhibit hysteresis?
Original language description
A simple fluid, in a microscopic capillary capped at one end, is studied by means of fundamental measure density functional. The model represents a single, infinitely long nanogroove with long-range wall-fluid attractive (dispersion) forces. It is shownthat the presence or absence of hysteresis in adsorption isotherms is determined by wetting properties of the wall as follows: Above wetting temperature, T-w, appropriate to a single wall of the groove, the adsorption is a continuous process corresponding to a rise of a meniscus from the capped to the open end of the groove. For a sufficiently deep capillary, the meniscus rise is shown to be a steep, yet continuous process taking place near the capillary condensation of a corresponding slit. However, for temperatures lower than T-w the condensation exhibits a first-order transition accompanied by hysteresis of the adsorption isotherm. Finally, it is shown that hysteresis may occur even for T } T-w as a consequence of prewetting on the s
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BJ - Thermodynamics
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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