Extraction of some univalent cations into phenyltrifluoromethyl sulfone by using sodium dicarbollylcobaltate in the presence of benzo-18-crown-6

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F13%3A43895000" target="_blank" >RIV/60461373:22340/13:43895000 - isvavai.cz</a>
Alternative codes found
RIV/46356088:_____/13:#0001379 RIV/60460709:41330/13:61060
Result on the web
<a href="http://dx.doi.org/10.1007/s10967-012-1803-1" target="_blank" >http://dx.doi.org/10.1007/s10967-012-1803-1</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10967-012-1803-1" target="_blank" >10.1007/s10967-012-1803-1</a>

Result language
angličtina
Original language name
Extraction of some univalent cations into phenyltrifluoromethyl sulfone by using sodium dicarbollylcobaltate in the presence of benzo-18-crown-6
Original language description
From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+ (aq) + 1 center dot Na+ (org) 1 center dot M+ (org) + Na+ (aq) taking place in the two-phase water-phenyltrifluoromethyl sulfone (abbrev. FS 13) system (M+ = Li+, H3O+, NH4 (+), Ag+, Tl+, K+, Rb+, Cs+; 1 = benzo-18-crown-6; aq = aqueous phase, org = FS 13 phase) were evaluated. Further, the stability constants of the 1 center dot M+ complexes in FS 13 saturated withwater were calculated; they were found to increase in the series of Cs+ { Rb+ { Ag+ { Li+ { NH4+ { K+ { Tl+.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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