Synergistic extraction of some univalent cations into nitrobenzene by using cesium dicarbollylcobaltate and calix[4]arene-bis(t-octylbenzo-18-crown-6)

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F13%3A43895006" target="_blank" >RIV/60461373:22340/13:43895006 - isvavai.cz</a>
Alternative codes found
RIV/46356088:_____/13:#0001375 RIV/60460709:41330/13:61053
Result on the web
<a href="http://dx.doi.org/10.1007/s10967-012-1897-5" target="_blank" >http://dx.doi.org/10.1007/s10967-012-1897-5</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10967-012-1897-5" target="_blank" >10.1007/s10967-012-1897-5</a>

Result language
angličtina
Original language name
Synergistic extraction of some univalent cations into nitrobenzene by using cesium dicarbollylcobaltate and calix[4]arene-bis(t-octylbenzo-18-crown-6)
Original language description
From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+ (aq) + CsL+ (nb) a double dagger" ML+ (nb) + Cs+ (aq) taking place in the two-phase water-nitrobenzene system (M+ =K+, Rb+, , Ag+, Tl+; L = calix[4]arene-bis(t-octylbenzo-18-crown-6); aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the ML+ complexes in nitrobenzene saturated with water were calculated; they were found to increase in the following cation order: { K+ { Ag+ { Rb+ { Tl+.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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