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Complexation of some univalent organic cations with hexaethyl p-tert-butylcalix[6]arene hexaacetate in nitrobenzene saturated water

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F13%3A43895010" target="_blank" >RIV/60461373:22340/13:43895010 - isvavai.cz</a>

  • Alternative codes found

    RIV/46356088:_____/13:#0001370 RIV/60460709:41330/13:61041

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s10967-012-2216-x" target="_blank" >http://dx.doi.org/10.1007/s10967-012-2216-x</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s10967-012-2216-x" target="_blank" >10.1007/s10967-012-2216-x</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Complexation of some univalent organic cations with hexaethyl p-tert-butylcalix[6]arene hexaacetate in nitrobenzene saturated water

  • Original language description

    From extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium C+(aq) + 1 center dot Cs+(nb) a double dagger"1 center dot C+ (nb) + Cs+(aq) taking place in the two-phase water-nitrobenzene system (C+ = methylammonium, ethylammonium, propylammonium, ethanolammonium, diethanolammonium, triethanolammonium, protonated tyramine, protonated dopamine, protonated DL-noradrenaline; 1 = hexaethyl p-tert-butylcalix[6]arene hexaacetate; aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Furthermore, the stability constants of the 1 center dot C+ complex species in nitrobenzene saturated with water were calculated; they were found to increase in the following cation order: protonatedtyramine { protonated dopamine { triethanolammonium { diethanolammonium { protonated DL-noradrenaline { propylammonium { ethanolammonium { ethylammonium { methylammonium.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CB - Analytical chemistry, separation

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Radioanalytical and Nuclear Chemistry

  • ISSN

    0236-5731

  • e-ISSN

  • Volume of the periodical

    295

  • Issue of the periodical within the volume

    3

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    5

  • Pages from-to

    2077-2081

  • UT code for WoS article

    000314895400062

  • EID of the result in the Scopus database