On the complexation of some univalent cations with 1,3-alternate-25,27-bis(1-octyloxy)calix[4]arene-crown-6 in nitrobenzene saturated with water

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F13%3A43895049" target="_blank" >RIV/60461373:22340/13:43895049 - isvavai.cz</a>
Alternative codes found
RIV/46356088:_____/13:#0001428 RIV/60460709:41330/13:60891
Result on the web
<a href="http://dx.doi.org/10.1007/s10847-012-0167-z" target="_blank" >http://dx.doi.org/10.1007/s10847-012-0167-z</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10847-012-0167-z" target="_blank" >10.1007/s10847-012-0167-z</a>

Result language
angličtina
Original language name
On the complexation of some univalent cations with 1,3-alternate-25,27-bis(1-octyloxy)calix[4]arene-crown-6 in nitrobenzene saturated with water
Original language description
From extraction experiments and gama-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+(aq) + 1?Cs+ (nb) = 1?M+nb) + Cs+ (aq) taking place in the two-phase water-nitrobenzene system (M+ = Ag+, K+, Rb+, Tl+; 1 = 1,3-alternate-25,27-bis(1-octyloxy)calix[4]arene-crown-6; aq is aqueous phase, nb is nitrobenzene phase) were determined. Moreover, the stability constants of the 1?M+ complexes in water-saturated nitrobenzene were calculated; they were found to increase in the series of K+ { Rb+ { Ag+ { Tl+.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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