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Derivation of the permeation equation for diffusion of gases and vapors in flat membrane by using Laplace transform

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F13%3A43895276" target="_blank" >RIV/60461373:22340/13:43895276 - isvavai.cz</a>

  • Result on the web

    <a href="http://www.tandfonline.com/doi/abs/10.1080/19443994.2013.770273#.UrQ2GFOXmM8" target="_blank" >http://www.tandfonline.com/doi/abs/10.1080/19443994.2013.770273#.UrQ2GFOXmM8</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1080/19443994.2013.770273" target="_blank" >10.1080/19443994.2013.770273</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Derivation of the permeation equation for diffusion of gases and vapors in flat membrane by using Laplace transform

  • Original language description

    Generally, the model of forced diffusion of a penetrant through nonporous polymer membranes can be quantitatively described by a partial differential equation of parabolic type, which is known as Fick's second law. In this article, the detailed explanation of application of the integral transform method (especially Laplace transform) for the solution of Fick's second law at given initial and boundary conditions is presented. Obtained final expression for the concentration profile inside a flat membraneand the diffusion flux through a membrane were verified on permeability data of carbon dioxide and cyclohexane through low-density polyethylene membrane. While CO2 permeation data can be successfully fitted by obtained model, in the case of cyclohexane vapors, when the diffusion coefficient cannot be supposed to be constant due to strong polymer-penetrant interactions (swelling), the agreement between model and experimental data is lower.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP106%2F10%2F1194" target="_blank" >GAP106/10/1194: Separation of volatile organic compounds from air</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Desalination and Water Treatment

  • ISSN

    1944-3994

  • e-ISSN

  • Volume of the periodical

    51

  • Issue of the periodical within the volume

    22-24

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    7

  • Pages from-to

    4343-4349

  • UT code for WoS article

    000320503800011

  • EID of the result in the Scopus database