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Thermal properties and homogenity range of Bi24 xCo2-xO39 ceramics

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F13%3A43895433" target="_blank" >RIV/60461373:22340/13:43895433 - isvavai.cz</a>

  • Alternative codes found

    RIV/60461373:22310/13:43895433

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Thermal properties and homogenity range of Bi24 xCo2-xO39 ceramics

  • Original language description

    Samples with different Bi2O3/Co2O3, ratio were prepared by ceramic route. Based on the results of DTA, XRD and SEM - EDX a section of phase diagram of the Bi-Co-O diagram in air atmosphere was calculated using the FactSage software. The sillenite structure of Bi24+xCo2-xO39 was confirmed and described. The Rietveld analysis confirmed SEM - EDX results. The heat capacity and enthalpy increments of Bi24Co2O39 were measured by differential scanning calorimetry (DSC) from 258 K to 355 K and by the drop calorimetry from 573 K to 973 K Above room temperature the temperature dependence of the molar heat capacity in the form C-pm = (1467.87 + 0.299410 . T - 15888378 . T-2) J K-1 mol(-1) was derived by least-squares method from the experimental data

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2013

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Ceramics-Silikáty

  • ISSN

    0862-5468

  • e-ISSN

  • Volume of the periodical

    57

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    4

  • Pages from-to

    83-86

  • UT code for WoS article

    000324568600001

  • EID of the result in the Scopus database