Local kinetics and thermodynamics of rapid electrochemical reactions
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F14%3A43897820" target="_blank" >RIV/60461373:22340/14:43897820 - isvavai.cz</a>
Result on the web
<a href="http://journals.aps.org/pre/abstract/10.1103/PhysRevE.89.042403" target="_blank" >http://journals.aps.org/pre/abstract/10.1103/PhysRevE.89.042403</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1103/PhysRevE.89.042403" target="_blank" >10.1103/PhysRevE.89.042403</a>
Alternative languages
Result language
angličtina
Original language name
Local kinetics and thermodynamics of rapid electrochemical reactions
Original language description
We introduce and discuss a local kinetic mechanism for an n-electron electrochemical reaction at the interface formed by an electrode and diluted electrolyte. We show that the suggested mechanism is in agreement with the Nernst equation in the thermal equilibrium. We also qualitatively characterize the structure of a flat electrodediluted electrolyte boundary in the meaning of the spatial distribution of electrochemical reactants and electric potential. As the suggested kinetic mechanism is not limitedby the duration of relaxation processes in electric double layers, it is suitable for the understanding and simulation of fast transient processes that appear in modern applications such as nanocolloid dielectrophoresis, AC electrospray, AC electroosmosis, or nanopore biosensing.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BK - Liquid mechanics
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA14-01781S" target="_blank" >GA14-01781S: Investigation on fluid mechanics in smart microsystems driven by electric fields</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Physical Review E
ISSN
1539-3755
e-ISSN
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Volume of the periodical
89
Issue of the periodical within the volume
4
Country of publishing house
US - UNITED STATES
Number of pages
4
Pages from-to
"042403-1"-"042403-4"
UT code for WoS article
000333983100004
EID of the result in the Scopus database
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