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Local kinetics and thermodynamics of rapid electrochemical reactions

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F14%3A43897820" target="_blank" >RIV/60461373:22340/14:43897820 - isvavai.cz</a>

  • Result on the web

    <a href="http://journals.aps.org/pre/abstract/10.1103/PhysRevE.89.042403" target="_blank" >http://journals.aps.org/pre/abstract/10.1103/PhysRevE.89.042403</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1103/PhysRevE.89.042403" target="_blank" >10.1103/PhysRevE.89.042403</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Local kinetics and thermodynamics of rapid electrochemical reactions

  • Original language description

    We introduce and discuss a local kinetic mechanism for an n-electron electrochemical reaction at the interface formed by an electrode and diluted electrolyte. We show that the suggested mechanism is in agreement with the Nernst equation in the thermal equilibrium. We also qualitatively characterize the structure of a flat electrodediluted electrolyte boundary in the meaning of the spatial distribution of electrochemical reactants and electric potential. As the suggested kinetic mechanism is not limitedby the duration of relaxation processes in electric double layers, it is suitable for the understanding and simulation of fast transient processes that appear in modern applications such as nanocolloid dielectrophoresis, AC electrospray, AC electroosmosis, or nanopore biosensing.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BK - Liquid mechanics

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA14-01781S" target="_blank" >GA14-01781S: Investigation on fluid mechanics in smart microsystems driven by electric fields</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Physical Review E

  • ISSN

    1539-3755

  • e-ISSN

  • Volume of the periodical

    89

  • Issue of the periodical within the volume

    4

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    4

  • Pages from-to

    "042403-1"-"042403-4"

  • UT code for WoS article

    000333983100004

  • EID of the result in the Scopus database