Synergistic extraction of some univalent cations into nitrobenzene by using cesium dicarbollylcobaltate and calix[4]arene-(2,3-naphthylene-crown-6,crown-6)

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F15%3A43899446" target="_blank" >RIV/60461373:22340/15:43899446 - isvavai.cz</a>
Alternative codes found
RIV/60460709:41330/15:68296
Result on the web
<a href="http://dx.doi.org/10.1016/j.molliq.2015.03.060" target="_blank" >http://dx.doi.org/10.1016/j.molliq.2015.03.060</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molliq.2015.03.060" target="_blank" >10.1016/j.molliq.2015.03.060</a>

Result language
angličtina
Original language name
Synergistic extraction of some univalent cations into nitrobenzene by using cesium dicarbollylcobaltate and calix[4]arene-(2,3-naphthylene-crown-6,crown-6)
Original language description
On the basis of extraction experiments and gamma-activity measurements, the exchange extraction constants corresponding to the general equilibrium M+ (aq) + 1.Cs+ (nb) reversible arrow 1.M+ (nb) + Cs+ (aq) occurring in the twophase water nitrobenzene system (M+ = NH4+, K+, Rb+, Ag+, Tl+; 1 = calix[4]arene-(2,3-naphthylene-crown-6,crown-6); aq = aqueous phase, nb = nitrobenzene phase) were evaluated. Moreover, the stability constants of the proven 1.M+ cationic complexes were calculated; they were foundto increase in the cation sequence of NH4+ <K+ < Rb+ < Cs+ < Ag+ < Tl+.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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