Thermophysical properties of aqueous solutions of the 1-ethyl-3-methylimidazolium tricyanomethanide ionic liquid

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F15%3A43899704" target="_blank" >RIV/60461373:22340/15:43899704 - isvavai.cz</a>

Result on the web

<a href="http://www.sciencedirect.com/science/article/pii/S0021961415001433" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0021961415001433</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jct.2015.05.011" target="_blank" >10.1016/j.jct.2015.05.011</a>

Result language

angličtina

Original language name

Thermophysical properties of aqueous solutions of the 1-ethyl-3-methylimidazolium tricyanomethanide ionic liquid

Original language description

Thermophysical behavior of the binary system [water+1-ethyl-3-methylimidazolium tricyanomethanide ionic liquid (IL)] was thoroughly characterized through systematic measurements of vapor-liquid equilibria (water activity a_w ), mixing enthalpy, density,viscosity, and refractive index. The measurements were performed in the entire composition range and/or specifically in the highly dilute IL region, at 298.15 K or as a function of temperature in the range from (288.15 to 318.15) K. Effective experimental methods minimizing IL sample consumption, using flow arrangements, instrument couplings and high degree of automation were preferably employed. In particular, the a_w determination based on the chilled-mirror dew point technique and implemented by an AquaLab 4TE instrument was identified as a generally superior approach to study VLE of (water+IL) systems. Excess thermodynamic properties(GE, HE, CpE, VE) and property deviations from the linear mixing rule (viscosity, refractive index) w

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

BJ - Thermodynamics

OECD FORD branch

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Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2015

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Chemical Thermodynamics

ISSN

0021-9614

e-ISSN

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Volume of the periodical

89

Issue of the periodical within the volume

October 2015

Country of publishing house

GB - UNITED KINGDOM

Number of pages

8

Pages from-to

169-176

UT code for WoS article

000357616800024

EID of the result in the Scopus database

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