Electrochemical characteristics of ideal polarizable interfaces with limited number of charge carriers
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F15%3A43900199" target="_blank" >RIV/60461373:22340/15:43900199 - isvavai.cz</a>
Result on the web
<a href="http://journals.aps.org/pre/abstract/10.1103/PhysRevE.92.052404" target="_blank" >http://journals.aps.org/pre/abstract/10.1103/PhysRevE.92.052404</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1103/PhysRevE.92.052404" target="_blank" >10.1103/PhysRevE.92.052404</a>
Alternative languages
Result language
angličtina
Original language name
Electrochemical characteristics of ideal polarizable interfaces with limited number of charge carriers
Original language description
Recent progress in material chemistry and surface engineering has led to emergence of new electrode materials with unique physical and electrochemical properties. Here, we introduce a physical model describing charging of ideal polarizable electrode-electrolyte interface where the electrode is characterized by a limited capacity to store charge. The analytical model treats the electrode and electrolyte phases as independent nonlinear capacitors that are eventually coupled through the condition of equality of the total stored electrical charge opposite in sign. Gouy-Chapman and condensed layer theories applied to a general 1 : n valent electrolyte are used to predict dependencies of differential capacitance of the electrolyte phase and surface concentration of the electrical charge on the applied potential. The model of the nonlinear capacitor for the electrode phase is described by a theory of electron donors and acceptors present in conductive solids as a result of thermal fluctuation
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BK - Liquid mechanics
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA14-01781S" target="_blank" >GA14-01781S: Investigation on fluid mechanics in smart microsystems driven by electric fields</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Physical Review E
ISSN
1539-3755
e-ISSN
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Volume of the periodical
92
Issue of the periodical within the volume
5
Country of publishing house
US - UNITED STATES
Number of pages
11
Pages from-to
"052404-1"-"052404-11"
UT code for WoS article
000365001900006
EID of the result in the Scopus database
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