Solvent extraction of trivalent europium and americium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and bis(diphenylphosphino)acetylene dioxide
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F16%3A43901674" target="_blank" >RIV/60461373:22340/16:43901674 - isvavai.cz</a>
Alternative codes found
RIV/60460709:41330/16:71241 RIV/00216224:14310/16:00094255
Result on the web
<a href="http://dx.doi.org/10.1016/j.molliq.2016.05.028" target="_blank" >http://dx.doi.org/10.1016/j.molliq.2016.05.028</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molliq.2016.05.028" target="_blank" >10.1016/j.molliq.2016.05.028</a>
Alternative languages
Result language
angličtina
Original language name
Solvent extraction of trivalent europium and americium into nitrobenzene by using a synergistic mixture of hydrogen dicarbollylcobaltate and bis(diphenylphosphino)acetylene dioxide
Original language description
Extraction of microamounts of europium and americium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B-) in the presence of bis(diphenylphosphino)acetylene dioxide (DPPADO, L) was investigated. The equilibrium data were explained assuming that the species HL+, ML3+, ML23+, and ML33+ (M3+ = Eu3+, Am3+) are extracted into the organic phase. The values of extraction and stability constants of the complex species in nitrobenzene saturated with water were determined. It was found that the stability constants of the corresponding complexes EuLn3+ and AmLn3+, where n = 1,2,3 and L is DPPADO, in water-saturated nitrobenzene are comparable or the same, respectively.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CB - Analytical chemistry, separation
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Molecular Liquids
ISSN
0167-7322
e-ISSN
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Volume of the periodical
221
Issue of the periodical within the volume
neuvedeno
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
5
Pages from-to
574-578
UT code for WoS article
000383004100072
EID of the result in the Scopus database
2-s2.0-84975105871