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Ionic liquid 1-ethyl-3-methylimidazolium tetracyanoborate: An efficient entrainer to separate methanol dimethyl carbonate azeotropic mixture

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F16%3A43902411" target="_blank" >RIV/60461373:22340/16:43902411 - isvavai.cz</a>

  • Result on the web

    <a href="http://www.sciencedirect.com/science/article/pii/S037838121630214X" target="_blank" >http://www.sciencedirect.com/science/article/pii/S037838121630214X</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.fluid.2016.04.021" target="_blank" >10.1016/j.fluid.2016.04.021</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Ionic liquid 1-ethyl-3-methylimidazolium tetracyanoborate: An efficient entrainer to separate methanol dimethyl carbonate azeotropic mixture

  • Original language description

    The ionic liquid (IL) 1-ethyl-3-methylimidazolium tetracyanoborate [EMIM][TCB] was studied as an agent for the separation of the methanol + dimethyl carbonate (DMC) azeotropic mixture by extractive distillation. Isothermal vapor-liquid equilibria of the methanol + DMC binary system and the ternary system with the IL were measured by headspace gas chromatography (HSGC) to examine the effect of the IL additive on the separation factor. The measurements were conducted at 336.2 K, a temperature close to the normal boiling point of the methanol + DMC azeotropic mixture, and at various compositions keeping constant IL mole fractions x(3) = (0.05, 0.10, 0.50). The new binary and ternary VLE data together with previously measured infinite dilution activity coefficients of methanol and DMC in [EMIM][TCB] were correlated well by the NRTL excess Gibbs energy model yielding their description at the level of experimental uncertainty. We found that [EMIM][TCB] increases the methanol/DMC separation factor considerably, thus eliminating the isovolatility behavior at quite low IL contents (x(3) > 0.080 at 101.325 kPa). Compared to other IL and non-IL entrainers studied for the purpose in the literature, [EMIM][TCB] ranks among the best performing ones, though its prohibitively high price would certainly hinder the process application at present.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Fluid Phase Equilibria

  • ISSN

    0378-3812

  • e-ISSN

  • Volume of the periodical

    423

  • Issue of the periodical within the volume

    September

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    8

  • Pages from-to

    120-127

  • UT code for WoS article

    000378961800013

  • EID of the result in the Scopus database

    2-s2.0-84966348856