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Calorimetric and FTIR study of selected aliphatic heptanols

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F16%3A43902521" target="_blank" >RIV/60461373:22340/16:43902521 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11320/16:10332051

  • Result on the web

    <a href="http://www.sciencedirect.com/science/article/pii/S0378381216301698" target="_blank" >http://www.sciencedirect.com/science/article/pii/S0378381216301698</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.fluid.2016.04.003" target="_blank" >10.1016/j.fluid.2016.04.003</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Calorimetric and FTIR study of selected aliphatic heptanols

  • Original language description

    Isobaric liquid phase heat capacities of nine selected aliphatic heptanols (1-heptanol, CAS RN: 111-70-6; 3-heptanol, CAS RN: 589-82-2; 4-heptanol, CAS RN: 589-55-9; 2-methyl-2-hexanol, CAS RN: 625-23-0; 5-methyl-2-hexanol, CAS RN: 627-59-8; 2-methyl-3-hexanol, CAS RN: 617-29-8; 3-ethyl-3-pentanol, CAS RN: 597-49-9; 2,2-dimethyl-3-pentanol, CAS RN: 3970-62-5; 2,4-dimethyl-3-pentanol, CAS RN: 600-36-2) were measured with a highly sensitive Tian-Calvet calorimeter in the temperature range from 261 K to 382 K. Experimental heat capacity data were correlated as a function of temperature. For eight compounds, a maximum on temperature dependence of heat capacity was observed. The phase behavior was investigated with a differential scanning calorimeter. Calorimetric measurements were complemented by FTIR spectroscopy from room temperature to a maximum of 428 K. The main aim of this work was to fill the gap in reliable heat capacity data for these compounds and to extend the knowledge base required for a better understanding of alcohols self-association.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BJ - Thermodynamics

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    S - Specificky vyzkum na vysokych skolach

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Fluid Phase Equilibria

  • ISSN

    0378-3812

  • e-ISSN

  • Volume of the periodical

    423

  • Issue of the periodical within the volume

    7 April 2016

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    12

  • Pages from-to

    43-54

  • UT code for WoS article

    000378961800006

  • EID of the result in the Scopus database

    2-s2.0-84964434554