Vapor?Liquid Equilibria for Binary Mixtures of Methyl Nonafluorobutyl Ether + Acetone, Cyclopentyl Methyl Ether, Ethyl Acetate, n-Heptane, Methanol, and Toluene.ne, Cyclopentyl Methyl Ether, Ethyl Acetate, n-Heptane, Methanol, and Toluene
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F17%3A43913487" target="_blank" >RIV/60461373:22340/17:43913487 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/acs.jced.7b00599" target="_blank" >http://dx.doi.org/10.1021/acs.jced.7b00599</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.jced.7b00599" target="_blank" >10.1021/acs.jced.7b00599</a>
Alternative languages
Result language
angličtina
Original language name
Vapor?Liquid Equilibria for Binary Mixtures of Methyl Nonafluorobutyl Ether + Acetone, Cyclopentyl Methyl Ether, Ethyl Acetate, n-Heptane, Methanol, and Toluene.ne, Cyclopentyl Methyl Ether, Ethyl Acetate, n-Heptane, Methanol, and Toluene
Original language description
Measurements of vapor-liquid equilibrium data in binary systems methyl nonafluorobutyl ether + solvent (acetone, cyclopentyl methyl ether, ethyl acetate, n-heptane, methanol, and toluene) were carried out at constant temperature (328.15 or 318.15 K) by means of a vapor-liquid equilibrium circulation still. In the most cases, the acquired data satisfied thermodynamic consistency tests. The obtained vapor-liquid equilibrium data were (successfully) correlated by two principally different thermodynamic models: the nonrandom two-liquid equation for the excess Gibbs energy, and the perturbed-chain statistical associating fluid theory equation of state. The latter model was tested also for its predictive capabilities and was found not to be suitable for reliable predictions in the studied binary systems, although it may correctly predict the azeotropic behavior of some systems.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
—
Continuities
S - Specificky vyzkum na vysokych skolach
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Chemical Engineering Data
ISSN
0021-9568
e-ISSN
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Volume of the periodical
62
Issue of the periodical within the volume
11
Country of publishing house
US - UNITED STATES
Number of pages
11
Pages from-to
3878-3888
UT code for WoS article
000415140900026
EID of the result in the Scopus database
2-s2.0-85033551032