Cation-π interaction of the Univalent Silver Cation with [2.2.2]Paracyclophane in the Gas Phase and in the Solid State: Experimental and Theoretical Study

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461373%3A22340%2F19%3A43917755" target="_blank" >RIV/60461373:22340/19:43917755 - isvavai.cz</a>
Alternative codes found
RIV/60460709:41330/19:81533 RIV/60461373:22810/19:43917755
Result on the web
<a href="https://link.springer.com/article/10.1007%2Fs10876-018-1461-8" target="_blank" >https://link.springer.com/article/10.1007%2Fs10876-018-1461-8</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10876-018-1461-8" target="_blank" >10.1007/s10876-018-1461-8</a>

Result language
angličtina
Original language name
Cation-π interaction of the Univalent Silver Cation with [2.2.2]Paracyclophane in the Gas Phase and in the Solid State: Experimental and Theoretical Study
Original language description
Employing electrospray ionization mass spectrometry, it was proven experimentally that the [2.2.2]paracyclophane-Ag+ complex (i.e., [Ag(C24H24)](+)) exists in the gas phase. Further, applying quantum chemical DFT calculations, the most probable structure of this cationic complex [Ag(C24H24)](+) was derived. Finally, in the solid state, the complex [2.2.2]paracyclophane-silver triflate-monohydrate (i.e., C24H24-AgCF3SO3-H2O), crystallizing in the monoclinic system with the centrosymmetric space group P2(1)/c, was prepared and analysed by X-ray crystallography.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry

Project
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Continuities
S - Specificky vyzkum na vysokych skolach<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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