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Temperature-related degradation and colour changes of historic paintings containing vivianite

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F60461446%3A52810%2F14%3A%230000167" target="_blank" >RIV/60461446:52810/14:#0000167 - isvavai.cz</a>

  • Alternative codes found

    RIV/60461446:52810/14:#0000180

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.saa.2014.12.082" target="_blank" >http://dx.doi.org/10.1016/j.saa.2014.12.082</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.saa.2014.12.082" target="_blank" >10.1016/j.saa.2014.12.082</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Temperature-related degradation and colour changes of historic paintings containing vivianite

  • Original language description

    Temperature-related degradation of pure synthetic as well as partly oxidised natural vivianite has been studied by high-temperature X-ray diffraction (HT-XRD) covering the whole extent of the temperaturerelated stability of its structure. While temperatures around 70°C are already damaging to vivianite, exposition to 160°C results in complete amorphisation of both the vivianite and its oxidation products. As indicated by Mössbauer spectroscopy, temperature-induced oxidation of vivianite starts at 90°C.To study the occurring structural as well as accompanying colour changes in more detail, model vivianite paint layer samples with different historic binders were prepared and subjected to increased temperatures. Exposition to 80°C caused pronounced colour changes of all the samples: ground natural blue vivianite became grey ? a colour change which has been described in actual works of art. Regarding the binders, the oil seemed to facilitate the transfer of heat to vivianite?s grains. To

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    AL - Art, architecture, cultural heritage

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP103%2F12%2F2211" target="_blank" >GAP103/12/2211: Methods for multimodal image processing based on mathematical models of optical properties of paint materials for artwork analysis</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy

  • ISSN

    1873-3557

  • e-ISSN

  • Volume of the periodical

    140

  • Issue of the periodical within the volume

    April

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    10

  • Pages from-to

    101-110

  • UT code for WoS article

  • EID of the result in the Scopus database