MODELING OF SYNTHESIS AND POLYMER PROPERTIES OF HOMOPOLYMER POLYPROPYLENE MATRIX
Result description
The results were presented at 2nd International Conference on Chemical Technology in Mikulov. The results describe the newly developed polymerization model, which enables the simulation of polypropylene homomatrix synthesis and its polymer properties. The polymerization model was developed on basis of a multidimensional regression analysis of experimental polymerization data. The experimental basis was relatively large, comprising the input parameters in the following ranges: TEA/ED molar ratio: 2 - 10mol/mol, polymerization temperature T: 60 - 90°C, hydrogen concentration H2/C3: 3.5 - 60 mmol/mol. The polymerizations were performed in 2-L laboratory stainless steel reactor at the polymerization conditions comparable to typical industrial polymerization processes. We utilize the newly developed polymerization model in the following ways: 1) prediction of catalyst activity and polymer properties under specified polymerization conditions, 2) construction of catalyst activity and polymer
Keywords
homopolymerization modelmodeling of polypropylene synthesismodeling of polypropylene properties
The result's identifiers
Result code in IS VaVaI
Result on the web
http://www.polymer.cz/Documents/Repository/Gruza_poster_fin.pdf
DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
MODELING OF SYNTHESIS AND POLYMER PROPERTIES OF HOMOPOLYMER POLYPROPYLENE MATRIX
Original language description
The results were presented at 2nd International Conference on Chemical Technology in Mikulov. The results describe the newly developed polymerization model, which enables the simulation of polypropylene homomatrix synthesis and its polymer properties. The polymerization model was developed on basis of a multidimensional regression analysis of experimental polymerization data. The experimental basis was relatively large, comprising the input parameters in the following ranges: TEA/ED molar ratio: 2 - 10mol/mol, polymerization temperature T: 60 - 90°C, hydrogen concentration H2/C3: 3.5 - 60 mmol/mol. The polymerizations were performed in 2-L laboratory stainless steel reactor at the polymerization conditions comparable to typical industrial polymerization processes. We utilize the newly developed polymerization model in the following ways: 1) prediction of catalyst activity and polymer properties under specified polymerization conditions, 2) construction of catalyst activity and polymer
Czech name
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Czech description
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Classification
Type
O - Miscellaneous
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Result continuities
Project
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
U - Předmět řešení projektu je utajovanou skutečností podle zvláštních právních předpisů nebo je skutečností, jejíž zveřejnění by mohlo ohrozit činnost zpravodajské služby. Údaje o projektu jsou upraveny tak, aby byly zveřejnitelné
Result type
O - Miscellaneous
CEP
CD - Macromolecular chemistry
Year of implementation
2014