Time-resolved Emission Spectra and TD-DFT Excited-state Calculations of [W(CO) 4 (1,10-phenanthroline)] and [W(CO) 4 (3,4,7,8-tetramethyl-1,10-phenanthroline)].

Result code in IS VaVaI

RIV/61388955:_____/01:54010054 - isvavai.cz

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Time-resolved Emission Spectra and TD-DFT Excited-state Calculations of [W(CO) 4 (1,10-phenanthroline)] and [W(CO) 4 (3,4,7,8-tetramethyl-1,10-phenanthroline)].

Original language description

Combined experimental and theoretical investigations show that the multiple emission from [W(CO) 4 (1,10-phenanthroline)] and [W(CO) 4 (3,4,7,8-tetramethyl-1,10-phenanthroline)] occurs from several MLCT excited states which originate in W-phen and W-CO excitations, respectively. Ligand-field excited states are not involved, lying at higher energies. Methylation of the phenanthroline ligand prolongs emission lifetimes but does not change the characters of the emissive states, despite the change in LUMO.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

OC D14.20: Oganometallic and Metallo-organic Building Blocks for Photonic Materials

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Inorganica Chimica Acta

ISSN

0020-1693

e-ISSN

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Volume of the periodical

315

Issue of the periodical within the volume

1

Country of publishing house

CH - SWITZERLAND

Number of pages

9

Pages from-to

44-52

UT code for WoS article

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EID of the result in the Scopus database

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