Ruthenium-Aminoallenylidene Complexes from Butatrienylidene Intermediates via an Aza-Cope Rearrangement: Synthetic, Spectroscopic, Electrochemical, Spectroelectrochemical and Computational Studies.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F01%3A54010059" target="_blank" >RIV/61388955:_____/01:54010059 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Ruthenium-Aminoallenylidene Complexes from Butatrienylidene Intermediates via an Aza-Cope Rearrangement: Synthetic, Spectroscopic, Electrochemical, Spectroelectrochemical and Computational Studies.

Original language description

Aminoallenylidene ruthenium complexes trans-[Cl(L2)2RuCCC(NR2)CH2R'] + EF6-(4a-f, E=P,Sb, L2=chelating diphosphine) were synthetised and characterized by various spectroscopic techniques including NMR-, IR-, and UV/Vis-spectroscopy, cyclic voltammetry. DFT calculations have been performed on model complexes trans-[Cl(L2)2Ru=C=C=C=CH2] + and trans-[Cl(L2)2RuC3{N(CH3)2}CH3] +. The calculations further indicate primarily metal based oxidation and ligand based reduction.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Organometallics

ISSN

0276-7333

e-ISSN

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Volume of the periodical

20

Issue of the periodical within the volume

7

Country of publishing house

US - UNITED STATES

Number of pages

17

Pages from-to

1317-1333

UT code for WoS article

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EID of the result in the Scopus database

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