Removal of CO Ligands from Pt Anionic Carbonyls in Zeolites by Heat Treatment in Vacuum or in Hydrogen Atmosphere and Following Subsequent Recarbonylation.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F01%3A54010085" target="_blank" >RIV/61388955:_____/01:54010085 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Removal of CO Ligands from Pt Anionic Carbonyls in Zeolites by Heat Treatment in Vacuum or in Hydrogen Atmosphere and Following Subsequent Recarbonylation.

Original language description

Pt anionic carbonyls were prepared by carbonylation of tetraamine ions in X, Y dealuminated Y, and EMT zeolites, by carbonylation of impregnated salts in MCM-41, NaBEA and NaM. These carbonyls were decomposed in vacuum and/or in hydrogen atmosphere and recarbonylated. It appeared that the recarbonylation after decomposition in vacuum proceeds readily in samples which exhibit higher basicity; with decreasing basicity carbonyls of higher nuclearity or lower negative charge are formed.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

<a href="/en/project/IAA4040710" target="_blank" >IAA4040710: Transition metal carbonyl complexes of high nuclearity in zeolite matrices and (sub)nanometer metallic clusters derived.</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Physical Chemistry Chemical Physics

ISSN

1463-9076

e-ISSN

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Volume of the periodical

3

Issue of the periodical within the volume

13

Country of publishing house

GB - UNITED KINGDOM

Number of pages

8

Pages from-to

2704-2711

UT code for WoS article

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EID of the result in the Scopus database

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