Electrochemical Oxidation of [Cr(CO) 4 (tmp)] to the Low-Spin Cr(I) Species [Cr(CO) 4 (tmp)] + (tmp=3,4,7,8-tetramethyl-1,10-phenanthroline): An IR,UV-Vis, and EPR Spectroelectrochemical and DFT Computational Study of the Accompanying Changes.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F01%3A54010102" target="_blank" >RIV/61388955:_____/01:54010102 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Electrochemical Oxidation of [Cr(CO) 4 (tmp)] to the Low-Spin Cr(I) Species [Cr(CO) 4 (tmp)] + (tmp=3,4,7,8-tetramethyl-1,10-phenanthroline): An IR,UV-Vis, and EPR Spectroelectrochemical and DFT Computational Study of the Accompanying Changes.

Original language description

[Cr(CO)4(tmp)] is elctrochemically ixidized to the corresponding cation vhich was characterized by EPR, IR, and UV-Vis spectroelectrochemistry at 193 K and by DFT calculations. It is a low-spin d5 Cr(I) complex. Oxidation is a accompanied by a large shift of electron density towards the Cr atom, manifested by a by nearly 100 cm-1 upward shift of the n(CO) IR bands. Spin density is lokalized mostly on the Cr atom but the charge on Cr is nearly the same both in the neutral and cationic complexes.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CG - Electrochemistry

OECD FORD branch

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Project

<a href="/en/project/OC%20D14.20" target="_blank" >OC D14.20: Oganometallic and Metallo-organic Building Blocks for Photonic Materials</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2001

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Inorganica Chimica Acta

ISSN

0020-1693

e-ISSN

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Volume of the periodical

318

Issue of the periodical within the volume

1

Country of publishing house

CH - SWITZERLAND

Number of pages

9

Pages from-to

143-151

UT code for WoS article

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EID of the result in the Scopus database

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