Influence of the Variation of the co-Ligands on the Electronic Transitions and Emission Properties of [Pt(I)(CH3)3(iPr-DAB)], [Pt(CH3)4 (-alfa.-diimine)] and [Pt(SnPh3)2(CH3)2(iPr-DAB)]: An Experimental and Theoretical Study.

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F02%3A54020049" target="_blank" >RIV/61388955:_____/02:54020049 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Influence of the Variation of the co-Ligands on the Electronic Transitions and Emission Properties of [Pt(I)(CH3)3(iPr-DAB)], [Pt(CH3)4 (-alfa.-diimine)] and [Pt(SnPh3)2(CH3)2(iPr-DAB)]: An Experimental and Theoretical Study.
Original language description
A combined spectroscopic (UV/Vis, resonance Raman), emission and theoretical study of Pt-diimine complexes is presented. The difference in character between the halide-to-ligand charge transfer (XLCT; X=I) transition of the first complex and the sigma-bond-to-ligand charge transfer (SBLCT) transitions of the others, is clearly established by resonance Raman (rR) spectroscopy. DFT MO calculations confirm the assignment of the frontier orbitals and lowest-energy electronic transitions.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2002
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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