Lactone Enols Are Stable in the Gas Phase but Highly Unstable in Solution.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F02%3A54020156" target="_blank" >RIV/61388955:_____/02:54020156 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Lactone Enols Are Stable in the Gas Phase but Highly Unstable in Solution.
Original language description
2-hydroxyoxol-2-one the enol tautomer of .gamma.-butyrolactone, was generated in the gas phase as the first representative of the hitherto elusive class of lactone enols and shown by neutralization-reionization mass spectrometry to be remarkably stable as an isolated species. The acid base properties of lactone enols point to their high reactivity in protic solvents and explain why no lactone enols have been detected thus far in solution studies.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2002
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of the American Chemical Society
ISSN
0002-7863
e-ISSN
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Volume of the periodical
124
Issue of the periodical within the volume
N/A
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
13282-13289
UT code for WoS article
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EID of the result in the Scopus database
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