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Lactone Enols Are Stable in the Gas Phase but Highly Unstable in Solution.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F02%3A54020156" target="_blank" >RIV/61388955:_____/02:54020156 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Lactone Enols Are Stable in the Gas Phase but Highly Unstable in Solution.

  • Original language description

    2-hydroxyoxol-2-one the enol tautomer of .gamma.-butyrolactone, was generated in the gas phase as the first representative of the hitherto elusive class of lactone enols and shown by neutralization-reionization mass spectrometry to be remarkably stable as an isolated species. The acid base properties of lactone enols point to their high reactivity in protic solvents and explain why no lactone enols have been detected thus far in solution studies.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2002

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of the American Chemical Society

  • ISSN

    0002-7863

  • e-ISSN

  • Volume of the periodical

    124

  • Issue of the periodical within the volume

    N/A

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    8

  • Pages from-to

    13282-13289

  • UT code for WoS article

  • EID of the result in the Scopus database