The .nu.(10)= 1 Level of Propyne, H3C-C=CH, and Its Interactions with .nu.(9)=1 and .nu.(10)=2.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F02%3A54020253" target="_blank" >RIV/61388955:_____/02:54020253 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
The .nu.(10)= 1 Level of Propyne, H3C-C=CH, and Its Interactions with .nu.(9)=1 and .nu.(10)=2.
Original language description
Almost 300 new rotational transitions within the fundamental vibrational level v(10)=1 of propyne have been measured in selected regions between 495 and 925 GHz spanning the quantum numbers 28less than or equal toJless than or equal to54 and 0less than or equal toKless than or equal to16. The accuracies are mostly between 10 and 20 kHz. In addition, the J'=4 and 5 transitions near 85 and 103 GHz have been remeasured. Simultaneous analyses with refined rovibrational data have been performed, showing thateven this lowest and seemingly isolated vibrational level needs a global treatment when high K transitions are involved. The global model with the v(10)=1 level coupled to the next higher cluster of levels, v(10)=2/v(9)=1, by Fermi and Coriolis resonances is necessary for a quantitative reproduction of both the rovibrational and rotational data within their experimental uncertainties.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GA203%2F01%2F1274" target="_blank" >GA203/01/1274: High-resolution molecular spectroscopy (with aspects in molecular physics, energy transfer, remote sensing of atmospheric pollutants, and metrology)</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2002
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Molecular Spectroscopy
ISSN
0022-2852
e-ISSN
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Volume of the periodical
216
Issue of the periodical within the volume
N/A
Country of publishing house
US - UNITED STATES
Number of pages
11
Pages from-to
397-407
UT code for WoS article
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EID of the result in the Scopus database
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