Redox Activation of Dicarbonyl(.eta.5-Cyclopentadienyl)Methyl Iron within the Cavity of .beta.-Cyclodextrin: Carbon Monoxide Insertion in Iron-Methyl Bond.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F03%3A54030021" target="_blank" >RIV/61388955:_____/03:54030021 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Redox Activation of Dicarbonyl(.eta.5-Cyclopentadienyl)Methyl Iron within the Cavity of .beta.-Cyclodextrin: Carbon Monoxide Insertion in Iron-Methyl Bond.

Original language description

The organometallic complex CpFe(CO)2CH3 is included in a .beta.-cyclodextrin cavity, retains its redox activity and undergoes CO insertion into the methyl-metal bond. The reaction inside the cavity suppresses undesirable loss of released CO from the reaction site. This simplifies the mechanism of the bond-insertion reaction in the presence of cyclodextrin. Further enhancement is observed in presence of free CO, which can penetrate to the reaction site inside the cyclodextrin cavity.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CG - Electrochemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2003

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Organometallic Chemistry

ISSN

0022-328X

e-ISSN

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Volume of the periodical

668

Issue of the periodical within the volume

1/2

Country of publishing house

CH - SWITZERLAND

Number of pages

8

Pages from-to

9-16

UT code for WoS article

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EID of the result in the Scopus database

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