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H+ and Na+ Ion Transport Properties of Sulfonated Poly(2,6-dimethyl-1,4-phenyleneoxide)Membranes.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F03%3A54030068" target="_blank" >RIV/61388955:_____/03:54030068 - isvavai.cz</a>

  • Alternative codes found

    RIV/61389013:_____/03:54030068

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    H+ and Na+ Ion Transport Properties of Sulfonated Poly(2,6-dimethyl-1,4-phenyleneoxide)Membranes.

  • Original language description

    Diffusion coefficients of H+ and Na+ ions in sulphonated poly(2,6-dimethyl-1,4- phenylene oxide) (PPO) intermolecularly complexed with poly(2-butylaniline) (PBA) or poly-[2,2Ž-(m-phenylene)-5,5Ž-bibenzimidazole] (PBI) were evaluated from conductivity andH+/Na+ ion exchange measurements. Ion exchange capacity and transport properties of the PPO membranes with a degree of sulphonation higher than 29 % are comparable to those of Nafion. Intermolecular complexing of sulphonated PPO membrane was found to improve its mechanical and chemical stability. The observed deterioration of ion exchange capacity and ion transport with increasing content of the complexing agent is related to the partial occupation of the fixed sulpho- groups by the tertiary nitrogen groups present in the PBA and PBI.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2003

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of the Electrochemical Society

  • ISSN

    0013-4651

  • e-ISSN

  • Volume of the periodical

    150

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    8

  • Pages from-to

    "E329"-"E336"

  • UT code for WoS article

  • EID of the result in the Scopus database