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Collisions of Slow Polyatomic Ions with Surfaces: The Scattering Method and Results.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F03%3A54030280" target="_blank" >RIV/61388955:_____/03:54030280 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Collisions of Slow Polyatomic Ions with Surfaces: The Scattering Method and Results.

  • Original language description

    Surface-induced dissociation and reactions in interactions of polyatomic ions with different surfaces (surfaces with self-assembled monolayers, carbon surfaces, hydrocarbon-covered metal surfaces) were studied using the scattering method. The experimental method is described. Energy transfer and partitioning of the incident projectile energy into internal excitation of the projectile, translational energy of products, and energy absorbed by the surface was determined from mass spectra, translational energy and angular distributions of the product ions. The distribution function for the translational-to-internal energy transfer peaks at 17% of the incident energy for the perfluoro-hydrocarbon SAM, and at about 6% for the other investigated surfaces. Theion survival probability is about 30-50x larger for closed-shell ions than for open-shell radical cations (e.g., 12% for CD5+ vs. 0.3% for CH4+, &#61510;N=600), and depends strongly on the incident angle.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2003

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of the American Society for Mass Spectrometry

  • ISSN

    1044-0305

  • e-ISSN

  • Volume of the periodical

    14

  • Issue of the periodical within the volume

    N/A

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    13

  • Pages from-to

    1360-1372

  • UT code for WoS article

  • EID of the result in the Scopus database