Zwitterionic complexes arising from the reaction of tucked-in titanocenes with tris(pentafluorophenyl)borane
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F05%3A00000578" target="_blank" >RIV/61388955:_____/05:00000578 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/05:00008810 RIV/00216208:11310/05:8810
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Zwitterionic complexes arising from the reaction of tucked-in titanocenes with tris(pentafluorophenyl)borane
Original language description
Single tucked-in titanocene [Ti(.eta.5-C5Me5)(.eta.5:.eta.1-C5Me4CH2)] adds to B(C6F5)3 to give the paramagnetic cationic complex [Ti(.eta.5-C5Me5){.eta.5-C5Me4CH2B(C6F5)3}] (1). Doubly tucked-in titanocene [Ti(.eta.5-C5Me5){.eta.:.eta.3:.eta.4-C5Me3(CH2)2}] reacts with B(C6F5)3 by one methylene group to give [Ti(.eta.5-C5Me5){.eta.5:.eta.1-C5Me3(CH2)CH2B(C6F5)3}] (6). The crystal structure of 6 revealed that one hydrogen of the methylene group attached to boron agostically interacts with Ti(IV).
Czech name
Kationtové komplexy vzniklé reakcí titanocenů obsahujícími methylenové skupiny s tris(pentafluorofenyl)boranem
Czech description
Titanocen s jednou methylenovou skupinou [Ti(.eta.5-C5Me5)(.eta.5:.eta.1-C5Me4CH2)] dává reakcí s B(C6F5)3 paramagnetický kationtový komplex [Ti(.eta.5-C5Me5){.eta.5-C5Me4CH2B(C6F5)3}] (1). Titanocen se dvěmi methylenovými skupinami [Ti(.eta.5-C5Me5){.eta.3:.eta.4-C5Me3(CH2)2}] reaguje s B(C6F5)3 pouze jednou methylenovou skupinou za vzniku komplexu [Ti(.eta.5-C5Me5){.eta.5:.eta.1-C5Me3(CH2)CH2B(C6F5)3}] (6). Krystalová struktura komplexu 6 ukazuje že jeden vodíkový atom z methylenové skupiny vázané k boru interaguje s Ti(IV) agostickou interakcí.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2005
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Inorganic Chemistry Communications
ISSN
1387-7003
e-ISSN
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Volume of the periodical
8
Issue of the periodical within the volume
2
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
5
Pages from-to
222-226
UT code for WoS article
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EID of the result in the Scopus database
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