Ligand-to-Diimine / Metal-to-Diimine Charge-Transfer Excited States of [Re(NCS)(CO)3(.alpha.-diimine)] (.alpha.-diimine = 2,2'-bipyridine, di- iPr-N,N-1,4-diazabutadiene). A Spectroscopic and Computational Study
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F05%3A00023801" target="_blank" >RIV/61388955:_____/05:00023801 - isvavai.cz</a>
Result on the web
—
DOI - Digital Object Identifier
—
Alternative languages
Result language
angličtina
Original language name
Ligand-to-Diimine / Metal-to-Diimine Charge-Transfer Excited States of [Re(NCS)(CO)3(.alpha.-diimine)] (.alpha.-diimine = 2,2'-bipyridine, di- iPr-N,N-1,4-diazabutadiene). A Spectroscopic and Computational Study
Original language description
Two new complexes fac-[Re(NCSKO)3(N,N)] (N,N = 2,2'-bipyridine (bpy), di- iPr-NN-1,4-diazabutadiene ( iPr-DAB)) were synthesized and their molecular structures determined by X-ray diffraction. UV-vis absorption, resonance Raman, emission, and picosecondtime-resolved IR spectra were measured experimentally and calculated with TD-DFT.
Czech name
Excitované stavy přenosu náboje ligand-diimin / kov-diimin v komplexech [Re(NCS)(CO)3(.alpha.-diimine)] (.alpha.-diimine = 2,2'-bipyridine, di- iPr-N,N-1,4-diazabutadiene). Spektroskopická a výpočetní studie
Czech description
Nové komplexy fac-[Re(NCS)(CO)3(N,N)] (N,N = 2,2'-bipyridin (bpy) di- iPr-N,N-1,4-diazabutadien, ( iPr-DAB)) byly syntesizovány a jejich molekulární struktury určeny rentgenovou difrační. UV-vis absorpční, resonanční Ramanovou, emisní a pikoekundovou časově rozlišenou IR spektroskopií a výpočty DFT.
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CG - Electrochemistry
OECD FORD branch
—
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2005
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Physical Chemistry. A
ISSN
1089-5639
e-ISSN
—
Volume of the periodical
109
Issue of the periodical within the volume
23
Country of publishing house
US - UNITED STATES
Number of pages
10
Pages from-to
5016-5025
UT code for WoS article
—
EID of the result in the Scopus database
—