Vibrational excitation and dissociative recombination of the LiH+ ion
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F07%3A00335352" target="_blank" >RIV/61388955:_____/07:00335352 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Vibrational excitation and dissociative recombination of the LiH+ ion
Original language description
LiH+ is one of the remaining enigmas among small, simple molecules, in its unexpectedly high dissociative recombination ( DR) rate. The dissociative recombination process, in which a colliding electron is captured, results in dissociation and destructionof the molecule. The conventional mechanism characteristic of most species with a high DR rate, which normally involves direct capture into a dissociative resonance potential curve, is absent here. For this reason, this is a prototype for indirect DR that must instead proceed through Rydberg capture pathways. We apply ab initio multichannel quantum defect theory ( MQDT), in combination with a rovibrational frame transformation based on Siegert pseudostates, to treat indirect DR for this fundamental diatomic ion. The starting point is a set of ab initio quantum defects determined using the R-matrix approach, functions of the internuclear distance.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2007
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Molecular Physics
ISSN
0026-8976
e-ISSN
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Volume of the periodical
105
Issue of the periodical within the volume
11-12
Country of publishing house
GB - UNITED KINGDOM
Number of pages
10
Pages from-to
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UT code for WoS article
000249780600010
EID of the result in the Scopus database
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