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Electrochemical impedance of nitrogen fixation mediated by fullerene-cyclodextrin complex

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F08%3A00310223" target="_blank" >RIV/61388955:_____/08:00310223 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Electrochemical impedance of nitrogen fixation mediated by fullerene-cyclodextrin complex

  • Original language description

    A water-soluble complex fullerene and .gamma.-cyclodextrin [C60(.gamma.CD)2] mediates an electrocatalytic conversion of dinitrogen to ammonia. The EIS data obtained under the atmosphere of argon or nitrogen were analyzed. A decrease of the charge-transfer resistance in the presence of nitrogen was found and used for selection of the most efficient potential for the electrochemical nitrogen fixation. Optimization was verified by the preparative electrolysis and detection of ammonia.

  • Czech name

    Elektrochemická impedance fixace dusíku v přítomnosti komplexu fuleren-cyklodextrin

  • Czech description

    Ve vodě rozpustný komplex fulerenu a .gamma.?cyklodextrinu [C60(.gamma.CD)2] zprostředkovává elektrokatalytickou konverzi dusíku na amoniak. Byla provedena analýza EIS pod atmosférou argonu a dusíku. Zjištěný pokles odporu přenosu náboje v přítomnosti dusíku byl využit pro výběr nejúčinnějšího potenciálu pro elektrochemickou fixaci dusíku. Za optimálních podmínek byla provedena preparativní elektrolýza a detekován amoniak.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CG - Electrochemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2008

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Electrochimica acta

  • ISSN

    0013-4686

  • e-ISSN

  • Volume of the periodical

    53

  • Issue of the periodical within the volume

    25

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    6

  • Pages from-to

  • UT code for WoS article

    000259015300012

  • EID of the result in the Scopus database