Heterogeneous catalysts containing basic and palladium centres for Heck reaction

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F08%3A00311887" target="_blank" >RIV/61388955:_____/08:00311887 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Heterogeneous catalysts containing basic and palladium centres for Heck reaction

Original language description

Heterogeneous catalysts for Heck reaction were prepared by the reaction of Pd(OAc)2 with various nitrogen pendants supported on mesoporous molecular sieves. The catalysts have been tested in the reaction of butyl acrylate with bromobenzene to give butylcinnamate. When the interaction of the aminogroups with palladium was too strong, the reaction proceeded rather slowly or not at all. Catalyst with N-{2-(N,N-diethyl-amino)ethyl}amine group reached 90% of conversion after 30 minutes of reaction. Moreover, this catalyst was able to catalyse the reaction even without an external base i.e., to act as bifunctional catalyst.

Czech name

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Czech description

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Type

C - Chapter in a specialist book

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2008

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Book/collection name

Zeolites and Related Materials: Trends, Targets and Challenges

ISBN

978-0-444-53298-5

Number of pages of the result

4

Pages from-to

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Number of pages of the book

1387

Publisher name

Elsevier

Place of publication

Oxford

UT code for WoS chapter

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